If you have turned ON both iCloud Photo Library and My Photo Stream on your device, then any photos you take with your iOS device or add to your photo library will be added to My Photo Stream. So, you can view and import those photos to any device which is not using iCloud Photo Library.
If you have enabled iCloud Photo Library and added photos to My Photo Stream, then those photos will be added to the "All Photos" album on your devices. Because when you turn ON iCloud Photo Library on your device, then the Camera Roll album is replaced with an "All Photos" album. You can also see all your photos and videos on iCloud.com.
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