Photos app for Mac groups all of your photos in a large library file. Photos app does not have the "Open In" feature, which is used to open a photo in another app. You must export the photo from Photos app before opening it in another application.
If you want to export photos from Photos app, select your photo and go to "File" menu and then select "Export" option. You will see 2 options i.e "Export X photos or videos" and "Export Unmodified Original". Choose any one option and select a file type, quality, size and naming convention.
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